extraordinary wave

synonym: extraordinary ray
https://doi.org/10.1351/goldbook.08600
In a uniaxial crystal electromagnetic radiation with electric vector oblique to the optic axis and which does not obey the normal laws of refraction.
Note:
In uniaxial crystals the optic axis coincides with the symmetry axis. The refractive index of the crystal is the same in all directions perpendicular to the optic axis but is different along the optic axis. Consequently, electromagnetic rays or waves that do not travel along the optic axis experience different refractive indices in different directions perpendicular to their direction of propagation. Two waves result, one has its electric vector perpendicular to the optic axis and forms the ordinary wave. The other is the extraordinary wave.
Source:
PAC, 2021, 93, 647. (Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)) on page 746 [Terms] [Paper]