crystalline electrodes

Also contains definitions of: heterogeneous membrane electrode, homogeneous membrane electrode
https://doi.org/10.1351/goldbook.C01431
Electrodes which contain mobile ions of one sign and fixed sites of opposite sign. They may be homogeneous or heterogeneous.
  1. Homogeneous
    membrane
    electrodes are ion-selective electrodes in which the
    membrane
    is a crystalline material prepared from either a single compound or a homogeneous mixture of compounds (i.e. Ag2S, AgI / Ag2S).
  2. Heterogeneous
    membrane
    electrodes are formed when an active substance, or mixture of active substances, is mixed with an
    inert
    matrix, such as silicone rubber or PVC, or placed on hydrophobized
    graphite
    or conducting epoxy, to form the heterogeneous sensing
    membrane
    .
Source:
PAC, 1994, 66, 2527. (Recommendations for nomenclature of ionselective electrodes (IUPAC Recommendations 1994)) on page 2534 [Terms] [Paper]