solvatochromism

https://doi.org/10.1351/goldbook.S05749
The (pronounced) change in position and sometimes intensity of an electronic absorption or emission band, accompanying a change in the polarity of the medium. Negative (positive) solvatochromism corresponds to a hypsochromic (bathochromic) shift with increasing solvent polarity.
See also: Dimroth–Reichardt ET parameter, Z-value
Sources:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1164 [Terms] [Paper]
PAC, 1996, 68, 2223. (Glossary of terms used in photochemistry (IUPAC Recommendations 1996)) on page 2274 [Terms] [Paper]
Citation: 'solvatochromism' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.S05749 RIS BibTex EndNote
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