strain

https://doi.org/10.1351/goldbook.S06037
Strain is present in a molecular entity or transition structure if the energy is enhanced because of unfavourable bond lengths, bond angles or dihedral angles ('torsional strain') relative to a standard. It is quantitatively defined as the standard enthalpy of a structure relative to a strainless structure (real or hypothetical) made up from the same atoms with the same types of bonding. (The enthalpy of formation of cyclopropane is 53.6 kJmol1, whereas the enthalpy of formation based on three 'normal' methylene groups, from acyclic models, is 62 kJmol1. On this basis cyclopropane is destabilized by ca. 115 kJmol1 of strain energy.)
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1168 [Terms] [Paper]